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1.
Proc Natl Acad Sci U S A ; 120(48): e2309379120, 2023 Nov 28.
Artículo en Inglés | MEDLINE | ID: mdl-37988469

RESUMEN

Chemical erosion, one of the two major erosion processes along with mechanical erosion, occurs when a soluble rock-like salt, gypsum, or limestone is dissolved in contact with a water flow. The coupling between the geometry of the rocks, the mass transfer, and the flow leads to the formation of remarkable patterns, like scallop patterns in caves. We emphasize the common presence of very sharp shapes and spikes, despite the diversity of hydrodynamic conditions and the nature of the soluble materials. We explain the generic emergence of such spikes in dissolution processes by a geometrical approach. Singularities at the interface emerge as a consequence of the erosion directed in the normal direction, when the surface displays curvature variations, like those associated with a dissolution pattern. First, we demonstrate the presence of singular structures in natural interfaces shaped by dissolution. Then, we propose simple surface evolution models of increasing complexity demonstrating the emergence of spikes and allowing us to explain at long term by coarsening the formation of cellular structures. Finally, we perform a dissolution pattern experiment driven by solutal convection, and we report the emergence of a cellular pattern following well the model predictions. Although the precise prediction of dissolution shapes necessitates performing a complete hydrodynamic study, we show that the characteristic spikes which are reported ultimately for dissolution shapes are explained generically by geometrical arguments due to the surface evolution. These findings can be applied to other ablation patterns, reported for example in melting ice.

2.
Proc Natl Acad Sci U S A ; 120(32): e2301947120, 2023 Aug 08.
Artículo en Inglés | MEDLINE | ID: mdl-37523527

RESUMEN

We show that unconstrained asymmetric dissolving solids floating in a fluid can move rectilinearly as a result of attached density currents which occur along their inclined surfaces. Solids in the form of boats composed of centimeter-scale sugar and salt slabs attached to a buoy are observed to move rapidly in water with speeds up to 5 mm/s determined by the inclination angle and orientation of the dissolving surfaces. While symmetric boats drift slowly, asymmetric boats are observed to accelerate rapidly along a line before reaching a terminal velocity when their drag matches the thrust generated by dissolution. By visualizing the flow around the body, we show that the boat velocity is always directed opposite to the horizontal component of the density current. We derive the thrust acting on the body from its measured kinematics and show that the propulsion mechanism is consistent with the unbalanced momentum generated by the attached density current. We obtain an analytical formula for the body speed depending on geometry and material properties and show that it captures the observed trends reasonably. Our analysis shows that the gravity current sets the scale of the body speed consistent with our observations, and we estimate that speeds can grow slowly as the cube root of the length of the inclined dissolving surface. The dynamics of dissolving solids demonstrated here applies equally well to solids undergoing phase change and may enhance the drift of melting icebergs, besides unraveling a primal strategy by which to achieve locomotion in active matter.

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